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Development of Cast Alumina-Forming Austenitic Stainless Steels

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Abstract

Cast Fe-Ni-Cr chromia-forming austenitic stainless steels with Ni levels up to 45 wt.% are used at high temperatures in a wide range of industrial applications that demand microstructural stability, corrosion resistance, and creep strength. Although alumina scales offer better corrosion protection at these temperatures, designing cast austenitic alloys that form a stable alumina scale and achieve creep strength comparable to existing cast chromia-forming alloys is challenging. This work outlines the development of cast Fe-Ni-Cr-Al austenitic stainless steels containing about 25 wt.% Ni with good creep strength and the ability to form a protective alumina scale for use at temperatures up to 800–850°C in H2O-, S-, and C-containing environments. Creep properties of the best alloy were comparable to that of HK-type cast chromia-forming alloys along with improved oxidation resistance typical of alumina-forming alloys. Challenges in the design of cast alloys and a potential path to increasing the temperature capability are discussed.

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Acknowledgements

Research sponsored by the US Department of Energy, Office of Energy Efficiency and Renewable Energy, Advanced Manufacturing Office, the Technology Innovation Program at Oak Ridge National Laboratory, and ARPA-E under Contract DE-AC05-00OR22725 with UT-Battelle, LLC.

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Authors and Affiliations

  1. Materials Science and Technology Division, Oak Ridge National Laboratory, 1 Bethel Valley Road, Oak Ridge, TN, 37831, USA

    G. Muralidharan, Y. Yamamoto, M. P. Brady, L. R. Walker, H. M. Meyer III & D. N. Leonard

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  1. G. Muralidharan
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  2. Y. Yamamoto
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  3. M. P. Brady
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  4. L. R. Walker
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  5. H. M. Meyer III
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  6. D. N. Leonard
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Correspondence to G. Muralidharan.

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Muralidharan, G., Yamamoto, Y., Brady, M.P. et al. Development of Cast Alumina-Forming Austenitic Stainless Steels. JOM 68, 2803–2810 (2016). https://doi.org/10.1007/s11837-016-2094-8

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  • DOI: https://doi.org/10.1007/s11837-016-2094-8

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